- In chemistry, a
thiyl radical has the
formula RS,
sometimes written RS• to
emphasize that they are free radicals. R is
typically an
alkyl or aryl substituent...
- 2±3.0 kcal/mol for X = O. Hydrogen-atom
abstraction from a
thiol gives a
thiyl radical with the
formula RS•,
where R =
alkyl or aryl.
Volatile thiols are...
-
additions can be
initiated by light, heat or
radical initiators,
which form a
thiyl radical species. The
radical then
propagates with an ene
functional group...
-
reaction can be
attributed to the
cleavage of
disulfide linkages (RS−SR) into
thiyl radicals (2 RS•)
which can
subsequently re****ociate into new bonds, resulting...
-
subunit and
differ by the
metal they use as cofactors. In
class II RNRs, the
thiyl radical is
generated using an
adenosylcobalamin cofactor and
these enzymes...
- Ni(II)),
which initiates formation of CH 4.
Coupling of the
coenzyme M
thiyl radical (RS.) with HS
coenzyme B
releases a
proton and re-reduces Ni(II)...
-
destroy odours or a
natural phenomenon. The
organic analogue of
sulfanyl is
thiyl radical with the
formula RS•,
where R is some
organic group (e.g., alkyl...
- Cys418, via Cys419 Cys418 (
thiyl radical) – does
acylation chemistry on the
carbon atom of the
pyruvate carbonyl Cys419 (
thiyl radical) –
performs hydrogen-atom...
-
surface of the
particles to form “staple”
motifs that have
significant Thiyl-Au(0) character. The citrate-gold surface, on the
other hand, is relatively...
-
Selectivity of
Radicals toward Double Bonds: The Case of a Tetrazole-Derived
Thiyl Radical Jacques Lalevée,
Xavier Allonas, and Jean
Pierre Fou****ier J. Org...
