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Disodium tetracarbonylferrate is the
organoiron compound with the
formula Na2[Fe(CO)4]. It is
always used as a solvate, e.g., with
tetrahydrofuran or dimethoxyethane...
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Examples include tetrachloroferrate ([FeCl4]2−),
oxyanions (FeO2− 4),
tetracarbonylferrate ([Fe(CO)4]2−), the organoferrates.[page needed] The term ferrate...
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cluster of
three iron
atoms at its core. Collman's reagent,
disodium tetracarbonylferrate, is a
useful reagent for
organic chemistry; it
contains iron in the...
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reagents such as iron pentacarbonyl,
diiron nonacarbonyl and
disodium tetracarbonylferrate.
Although iron is
generally less
active in many
catalytic applications...
- → Fe(CO)4I2 + CO
Reduction of Fe(CO)5 with Na
gives Na2Fe(CO)4, "
tetracarbonylferrate" also
called Collman's reagent. The
dianion is
isoelectronic with...
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cluster of
three iron
atoms at its core. Collman's reagent,
disodium tetracarbonylferrate, is a
useful reagent for
organic chemistry; it
contains iron in the...
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complex was
prepared by the salt
metathesis reaction of
disodium tetracarbonylferrate (Na 2Fe(CO)4) with 1,1-bis(chloromethyl)ethylene (H2C=C(CH2Cl)2)...
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salts of [FeO4]2−.
These include the
highly reduced species disodium tetracarbonylferrate Na2[Fe(CO)4], K2[Fe(CO)4] and
salts of the iron(III)
complex tetrachloroferrate...
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hydrochloric acid. In the
reaction of
phthalic anhydride with
sodium tetracarbonylferrate, only one of the
carboxyl groups is
reduced to the aldehyde, the...
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complexes requires indirect routes, such as the
reaction of
disodium tetracarbonylferrate with thiophosgene: Na2Fe(CO)4 + CSCl2 → Fe(CO)4CS + 2 NaCl Complexes...
