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Phosphinidenes (IUPAC: phosphanylidenes,
formerly phosphinediyls) are low-valent
phosphorus compounds analogous to
carbenes and nitrenes,
having the general...
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recent synthesis reported in 2019
proceeds through the
transfer of a
phosphinidene species from dibenzo-7-(R)-7-phospha-norbornadiene (RPA) onto styrene...
- 4-coordinate silicon,
which can also be
viewed as silylene-stabilized
phosphinidene, can be
synthesized based on the
reactivities of
stable silyene complexes...
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reacting with main-group
starting materials such as ylides, silylene, and
phosphinidene to
synthesize and
isolate for
further steps. As CO
becomes a more common...
- Wolczanski,
Peter T.; Lobkovsky, Emil B. (1994-11-01). "Arsinidene,
Phosphinidene, and
Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E...
- phosphanido, or dihydridophosphato(1−). A
related substance has PH2−.
Phosphinidene (PH) has
phosphorus in a −1
oxidation state. As a
ligand PH2 can either...
- R2N+ (protonated nitrenes)
phosphinidenium cations, R2P+ (protonated
phosphinidene)
mercurinium cations, R3Hg+ (protonated
organomercury compounds; formed...
- Fischer;
Andre Mitschler (1982). "Generation and
Trapping of
Terminal Phosphinidene Complexes.
Synthesis and X-ray
Crystal Structure of
Stable Phosphirene...
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synthesize free,
uncomplexed phosphet-2-ones with high
yield using a
phosphinidene transfer agent derived from anthracene. The
reactivity of the phosphet-2-ones...
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monomeric intermediate fragment. The V-NP
fragment undergoes singlet phosphinidene reactivity ([2+1] additions) with
alkene and
alkyne trapping agents...
