- Li and π-bound to Cu. However, the
existence of 'mixed
higher order organocuprates' has been
disputed by
Bertz and coworkers, who
rejoined that the cyano...
-
nucleophilic substitution by lower-order
organocuprates depends in a
profound way on the
structure of the substrate,
organocuprate, and
reaction conditions. Early...
-
usefully modified in the
present of
other metals. Copper(I)
salts give
organocuprates that
preferentially effect 1,4 addition.
Cerium trichloride allows selective...
- 1021/ja067533d. PMID 17506552. Hu, Haipeng; Snyder,
James P. (2007). "
Organocuprate Conjugate Addition: The Square-Planar "CuIII" Intermediate". Journal...
-
regeneration of
unsaturation following 1,4-addition with
nucleophiles such as
organocuprates. For
acyclic substrates the
reaction yields the
thermodynamic E-olefin...
- in
forming ketones from acyl chlorides. The
reaction also
works with
organocuprates.[5][6]
Reviews have been written.[7][8] The
mechanism is
sampled from...
- Rijs,
Richard A. J. O’Hair (2010-05-24). "Unimolecular
Reactions of
Organocuprates and Organoargentates". Organometallics. 29 (10): 2282–2291. doi:10.1021/om1000875...
-
inhibitors of 2,3-oxidosqualene-lanosterol cyclase:
conjugate addition of
organocuprates to N-(carbobenzyloxy)-3-carbomethoxy-5,6-dihydro-4-pyridone". Journal...
-
reacting alkyl lithium species with copper(I) halide. The
resulting organocuprates are
generally less
reactive toward aldehydes and
ketones than organolithium...
-
inhibitors of 2,3-oxidosqualene-lanosterol cyclase:
conjugate addition of
organocuprates to N-(carbobenzyloxy)-3-carbomethoxy-5,6-dihydro-4-pyridone". Journal...
