-
preparation of a
series of
strong photoreducing agents: Fac-tris-ortho-
metalated complexes of iridium(III) with
substituted 2-phenylpyridines". Inorganic...
-
quaternary ammonium salt is
involved or the aza-Wittig
reaction if an alpha-
metalated tertiary amine is involved; if Y is oxygen, then it is
called a 2,3-Wittig...
-
metalation is an
important class of
metalation reactions.
Metalated sulfones, acyl
groups and α-
metalated amides are
important intermediates in
chemistry synthesis...
- single-electron-transfer
mechanism of the type
shown below.
Magnesium similarly metalates organohalides to give
Grignard reagents. Frankland, E. (1849). "Ueber...
- base with an
electrophile such as
iodomethane gives N-methylpyrrole. N-
Metalated pyrrole can
react with
electrophiles at the N or C positions, depending...
- ISBN 978-0-471-26418-7. Yang, Xun; Fleming,
Fraser F. (2017). "C- and N-
Metalated Nitriles: The
Relationship between Structure and Selectivity". Accounts...
-
toluene using this reagent.
Benzene and cis/trans-2-butene are also
readily metalated by Schlosser's base. Toluene, benzene, and
butenes react only
slowly with...
- pH it
converts to
sodium decavanadate. It is also
precursor to
exotic metalates such as [γ-PV2W10O40]5-, [α-PVW11O40]4-, and [β-PV2W10O40]5-.
Sodium metavanadate...
- The
higher alkali metals are
known to
metalate even some
unactivated hydrocarbons and are
known to self-
metalate: 2 NaC2H5 → C2H4Na2 + C2H6 In the ****lyn...
- is the
result of
kinetically controlled diastereoselective addition of
metalated 1-phenyl-1H-tetrazol-5-yl (PT)
sulfones to
nonconjugated aldehydes. This...
