- isolated.
Primary ketimines can be
synthesized via a
Grignard reaction with a nitrile. This
method is
known as Moureu-Mignonac
ketimine synthesis. For example...
- to use
alkynyl ketimines as
synthetic equivalents of
dialkyl ketimines, and
dialkyl ketimes are a
typical example of
isomeric ketimine mixtures. The alkynyl...
- Solinas,
Sandro P.; Fontana,
Mario (1991). "Sulfur-containing
cyclic ketimines and
imino acids. A
novel family of
endogenous products in the
search for...
- They can be
considered a sub-class of imines,
being either secondary ketimines or
secondary aldimines depending on
their structure. Anil
refers to a...
- "Tertiary
Carbinamines by
Addition of
Organocerium Reagents to
Nitriles and
Ketimines".
Journal of
Organic Chemistry. 57 (16): 4521–7. doi:10.1021/jo00042a037...
-
synthesis of
chiral amines from
ketimines using a
chiral alkoxide. The
addition of a
phosphinoyl group to the
nitrogen of the
ketimine allowed for high enantioselectivity...
- intermediate.
Ketimine formation: The qui****id is reprotonated, but now at the
aldehyde carbon, to form the
ketimine intermediate.
Ketimine hydrolysis:...
- Volumes, vol. 4, p. 769. ****rd, P. L.; Tolbert, T. L. (1973). "Diphenyl
Ketimine".
Organic Syntheses;
Collected Volumes, vol. 5, p. 520. Anderson, Gordon...
-
Hydrazone R'R"CN2H2 hydrazino- -hydrazine
Imine Primary ketimine RC(=NH)R' imino- -imine
Secondary ketimine RC ( = NR ″ ) R ′ {\displaystyle {\ce {RC(=NR'')R'}}}...
- but
sometimes bound through the
central carbon only, see also
analogous ketimine analogues Alkenes R2C=CR2
neutral compounds with a C−C
double bond Aminopolycarboxylic...
