-
Imidoyl chlorides are
organic compounds that
contain the
functional group RC(NR')Cl. A
double bond
exist between the R'N and the
carbon centre. These...
- scale. This
reaction involves conversion of N,N-dimethylformamide to the
imidoyl chloride derivative (chloromethylene(dimethyl)ammonium ion (CH3)2N+=CHCl)...
-
reactive component of interest. This
iminium species is a
derivative of the
imidoyl chloride CH3N=CHCl.
Analogues of this
particular reagent are generated...
- reaction. Such
reactions are
believed to
proceed via an
imidoyl chloride. In
certain cases, the
imidoyl chloride is the
final product. For example, pyridones...
-
mainly used in the
Stephen reduction,
whereby a
nitrile is
reduced (via an
imidoyl chloride salt) to an
imine which is
easily hydrolysed to an aldehyde. The...
- 5-disubstituted and 1,4,5-trisubstituted
imidazoles from
aldimines and
imidoyl chlorides".
Journal of
Organic Chemistry. 42 (7): 1153–1159. Bibcode:1977JOrgC...
-
direct amination of nitriles. They are also
generated by
amination of an
imidoyl chloride. They are also
prepared by the
addition of
organolithium reagents...
-
thionyl chloride. The
catalytic mechanism entails reversible formation of an
imidoyl chloride (also
known as the 'Vilsmeier reagent'): DMF
penetrates most plastics...
- Bischler–Napieralski
reaction Cyclic aryl
imine POCl3, SOCl2, etc.
Tautomeric chlorination Imidoyl chloride Oxophilic halogenating agents, e.g. COCl2 or SOCl2...
-
analogous process primary amides will
react with
thionyl chloride to form
imidoyl chlorides, with
secondary amides also
giving chloroiminium ions. These...
