- In
organic chemistry,
hydroamination is the
addition of an N−H bond of an
amine across a carbon-carbon
multiple bond of an alkene, alkyne, diene, or allene...
- solution,
hydrogen gas and a
heterogeneous metallic ruthenium catalyst. In
hydroamination,
amines add to alkenes. Alkylation, the
addition of an
alkyl group Acylation...
- with an
alkene to form a
tertiary N-oxide. The
reaction is a form of
hydroamination and can be
extended to the use of
unsubstituted hydroxylamine, in which...
- Ian J.; Hill,
Michael S. (2005). "Calcium-Mediated
Intramolecular Hydroamination Catalysis".
Journal of the
American Chemical Society. 127 (7): 2042–43...
-
copper (I)
hydride catalyst and a
thermodynamically stable silanol. For
hydroaminations,
ligated copper (I)
hydride undergoes a 1,2
migratory insertion; the...
-
significantly as dihydroxymethane.
Conceptually similar reactions include hydroamination and hydroalkoxylation,
which involve adding amines and
alcohols to alkenes...
-
involving alkylation of
amines with alcohols, the
byproduct being water.
Hydroamination is
another green method for N-alkylation. In the
Menshutkin reaction...
- used
industrially to
produce tertiary amines such as tert-octylamine.
Hydroamination of
alkenes is also
widely practiced. The
reaction is
catalyzed by zeolite-based...
-
Joseph A. R. (1
January 2013). "Palladium
catalyzed intermolecular hydroamination of 1-substituted allenes: an atom-economical
method for the synthesis...
-
terminal alkynes with
amine groups using Cu2(OAc)4. It has been used for
hydroamination of acrylonitrile. It is also an
oxidising agent in Barfoed's test. It...
