-
local 6π
homoaromaticity can be
switched to a
global 10π
homoaromaticity. It was long
considered that the best
examples of
neutral homoaromatics are bishomoaromatics...
- boron) for "normal"
aromatic stabilization to be available; otherwise,
homoaromaticity may be possible.
Borazocine is an eight-membered ring with four nitrogen...
-
compounds called cyclophanes. A
special case of
aromaticity is
found in
homoaromaticity where conjugation is
interrupted by a
single sp³
hybridized carbon...
-
stability due to the
phenomenon called "three-dimensional aromaticity" or
homoaromaticity. This four-center two-electron bond
involves one pair of electrons...
-
Homonaphthalene has been used in the
production of
conductive polymers.
Homoaromaticity Cyclodecapentaene 1,5-Methano[10]annulene Vogel, Emanuel; Klug, W.;...
- 1964 in the
group of R. B.
Woodward in
connection with its
suspected homoaromatic properties—though it was
found to have no such properties—and also as...
-
Tetrahedral Topology.
Experimental Realization of Three-Dimensional
Homoaromaticity in the 1,3-Dehydro-5,7-adamantanediyl Dication".
Angewandte Chemie...
-
derived from
delocalization of
positive charge (see the
article on
homoaromaticity for details.).
Neutral systems generally require constrained geometries...
- 5-Methano[10]annulene, 1,5-methanoazulene or
homoazulene is a
hydrocarbon with
chemical formula C11H10.
Homoaromaticity Cyclodecapentaene 1,6-Methano[10]annulene v t e...
-
alphabet (α-γ) and the
substitution pattern nomenclature common for
homoaromatic systems (ortho, meta, para) are used sometimes. Here α (ortho), β (meta)...