- bis(trimethylsilyl)amide (commonly
abbreviated as KHMDS, Pot****ium(K)
HexaMethylDiSilazide) or pot****ium
hexamethyldisilazane is the
chemical compound with...
- Bis(trimethylsilyl)amine (also
known as
hexamethyldisilazane and HMDS) is an
organosilicon compound with the
molecular formula [(CH3)3Si]2NH. The molecule...
- LiN(Si(CH3)3)2. It is
commonly abbreviated as
LiHMDS or Li(HMDS) (lithium
hexamethyldisilazide - a
reference to its
conjugate acid HMDS) and is
primarily used as...
-
formula NaN(Si(CH3)3)2. This species,
usually called NaHMDS (sodium
hexamethyldisilazide), is a
strong base used for
deprotonation reactions or base-catalyzed...
- in
organometallic chemistry:
Hexamethyldisilazane ([(CH3)3Si]2NH)
Hexamethyldisilazide ([(CH3)3Si]2NM) M = Li as in
Lithium bis(trimethylsilyl)amide (LiHMDS)...
- P. G. (1997). "Effect of
Polydentate Donor Molecules on
Lithium Hexamethyldisilazide Aggregation: An X-ray
Crystallographic and a
Combination Semiempirical...
- doi:10.1039/C3GC41214H. Lucht, B. L.; Collum, D. B. (1999). "Lithium
Hexamethyldisilazide: A View of
Lithium Ion
Solvation through a Gl****-Bottom Boat". Accounts...
- Hydrogen-Bond
Donor into a
Weakly Nucleophilic Brønsted Base:
Alkali Metal Hexamethyldisilazides (MHMDS, M = Li, Na, K, Rb and Cs) with Ammonia". Chem. Eur. J. 22...
- (and more stable) enolate,
whilst reaction at −78 °C with pot****ium
hexamethyldisilazide, KN[Si(CH 3) 3] 2 and
triethylborane generates the less substituted...
- of
cosolvency in
oxazolidinone enolizations mediated by
lithium hexamethyldisilazide (LiHMDS). This
reaction pathway was
exemplified by the
group in the...
