- good
leaving group. In
organic chemistry,
fluorosulfonate is
different than fluorosulfate. In
fluorosulfonates,
sulfur atom is
directly bonded to a non-oxygen...
-
Methyl fluorosulfonate, also
known as
magic methyl, is the
organic compound with the
formula FSO2OCH3. It is a
colorless liquid that is used as a strong...
- The
fluorosulfates or
fluorosulfonates are a set of
salts of
fluorosulfuric acid with an ion
formula SO3F−. The
fluorosulfate anion can be
treated as though...
-
methylating reagents include methyl triflate, diazomethane, and
methyl fluorosulfonate (magic methyl).
These reagents all
react via SN2
nucleophilic substitutions...
- but much more violent.
Chlorosulfuric acid
Sulfuryl fluoride Methyl fluorosulfonate, an
organic ester of FSO3H
Trifluoromethylsulfonic acid Sigma-Aldrich...
-
methyl fluorosulfonate (FSO2OCH3).
Although there has yet to be a
reported human fatality,
several cases were
reported for
methyl fluorosulfonate (LC50...
- than
methyl sulfonate esters,
including methyl triflate and
methyl fluorosulfonate ("magic methyl"). Only the
exotic dimethylhalonium reagents ([Me2X]+[SbF6]−...
-
desired product: SO2ClF + KSO2F → SO2F2 + KCl + SO2
Heating metal fluorosulfonate salts also
gives this molecule: Ba(OSO2F)2 → BaSO4 + SO2F2 It can be...
- is
highly stabilized, a
reactive alkylating reagent, such as
methyl fluorosulfonate ("magic methyl" reagent) or
methyl bromoacetate is needed.
Aldol condensation...
- difluoro-λ3-bromane to
yield a
singly substituted N-sulfamoyl fluoride.
Fluorosulfonate Sulfonyl halide Sulfuryl fluoride Enders,
Dieter (2014).
Science of...
