-
using a
Grignard reagent and
carbon dioxide.
Dithiocarboxylate salts readily S-alkylate to give
dithiocarboxylate esters: RCS2Na + R'Cl → RCS2R' + NaCl Aryldithiocarboxylic...
- In
organic chemistry,
thiocarboxylic acids or
carbothioic acids are
organosulfur compounds related to
carboxylic acids by
replacement of one of the oxygen...
-
organolithium compounds degrade with loss of
ethylene to give the
dithiocarboxylate: RCLiS2C2H4 → RCS2Li + C2H4 In contrast, 2-lithio-1,3-dithianes (RCLiS2C3H6)...
- Its
conjugate base, dithiobenzoate,
undergoes S-alkylation to give
dithiocarboxylate esters. Similarly,
dithiobenzoate reacts with "soft"
metal salts to...
- substituent, the two
sulfur centers show
enhanced basicity relative to
dithiocarboxylates. This
situation is
represented by the
zwitterionic resonance structure...
- as a "trapping" reaction. With
addition of CS2 in THF, a
betainic dithiocarboxylate was synthesized, with its
crystal structure fully characterized and...
-
dithiocarbamates are more
basic than
structurally related anions such as
dithiocarboxylates and xanthates. Consequently, they tend to bind as
bidentate ligands...
