-
Substituted dicarbollides are also
known such as [C2B9H10(pyridine)]− (pyridine
bonded to B) and [C2R2B9H9]2- (R
groups bonded to carbon).
Dicarbollides are obtained...
- vertices. A well-developed
class of
metallacarboranes are
prepared from
dicarbollides,
anions of the
formula [C2B9H11]2-.
These anions function as ligands...
- Sivaev, I. B.; Bregadze, V. I. (2000). "Chemistry of
Nickel and Iron Bis(
dicarbollides). A Review".
Journal of
Organometallic Chemistry. 614–615: 27–36. doi:10...
-
motifs are also well studied, such as boranes,
carboranes and
metal dicarbollides.[citation needed] Nitrogen,
unlike its
neighbor carbon, is much less...
- Mirkin, Chad A. (June 28, 2010). "Electronic
Tuning of Nickel-Based Bis(
dicarbollide)
Redox Shuttles in Dye-Sensitized
Solar Cells". Angew. Chem. Int. Ed...
-
commercial applications.
Anionic derivatives such as [C2B9H11]2−,
called dicarbollides,
ligate similarly to cyclopentadienide. In borabenzene,
boron replaces...
-
metals and f-elements. The
dianion forms sandwich compounds, bis(
dicarbollides).
Dicarbollides,
being strong electron donors,
stabilize higher oxidation states...
- ****ler, C. B.; Hawthorne, M. F. (1991). "Syntheses of Charge-Compensated
Dicarbollide Ligand Precursors and
Their Use in the
Preparation of
Novel Metallacarboranes"...
-
polyhedral cages ranging in size from 6 to 15 vertices.
Examples include bis(
dicarbollide) complexes, such as [M(C2B9H11)2]z− and [Fe(C2B9H11)2]2−, and small-carborane...
-
ethylene glycol) and a
cobalt carborane anion (known as
chlorinated cobalt dicarbollide). The
actinides are
extracted by CMPO, and the
diluent is a
polar aromatic...
