-
obligate anaerobes Halogenated organic compounds R–X
Halide ions and
dehalogenated compound X− + R–H +0.25 – +0.60
Dehalococcoides and
Dehalobacter species...
-
metabolite as
electron acceptors for growth.
Iodinated compounds may be
dehalogenated as well,
though the
process may not
satisfy the need for an electron...
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available for this purpose.
Unlike iodine,
astatine shows a
tendency to
dehalogenate from
molecular carriers such as these,
particularly at sp3
carbon sites...
- 2-trifluoroethane) and halon-2402 (1,2-dibromo-1,1,2,2-tetrafluoroethane) can be
dehalogenated by the
action of
radiation on
alkaline isopropanol solutions. Again...
- In enzymology, a 2-chlorobenzoate 1,2-dioxygenase (EC 1.14.12.13) is an
enzyme that
catalyzes the
chemical reaction 2-chlorobenzoate + NADH + H+ + O2 ⇌...
- The
yield of this
reaction can be
improved by the use of zinc as the
dehalogenating agent and
sodium iodide as a catalyst. BrCH2CH2CH2Br + 2 Na → (CH2)3...
- alkyl/arene-magnesium-halogen compound,
followed by
addition of
proton source to form
dehalogenated product.
Egorov and his co-workers have
reported dehalogenation of benzyl...
-
photochemically because the carbon-halogen bond can be labile. Some
microorganisms dehalogenate halocarbons.
While this
behavior is intriguing, the
rates of remediation...
- Chromium(II)
acetate has few
practical applications. It has been used to
dehalogenate organic compounds such as α-bromoketones and chlorohydrins. The reactions...
- emplo**** to
generate alkyl zinc
reagents for
conjugate addition, as a
dehalogenating reagent, as a
promoter of
reductive coupling of
carbonyl compounds,...
