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Chemoselectivity is the
preferential reaction of a
chemical reagent with one of two or more
different functional groups. In a
chemoselective system, a...
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sacrificial alcohol. The
advantages of the MPV
reduction lie in its high
chemoselectivity and its use of a
cheap environmentally friendly metal catalyst. MPV...
- pH),
shorter reaction times,
higher yields,
simplified workups, high
chemoselectivity,
tolerance of
sensitive functional groups, and a long
shelf life. However...
- tolerated. In this sense,
chemoselectivity is
sometimes referred to as
functional group tolerance. Furthermore, high
chemoselectivity avoids often undesired...
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couple with
chlorinated arenes. This low
reactivity is the
basis for
chemoselectivity for
nickel insertion into the C–Br bond of
bromochlorobenzene using...
-
aromatic ring to give
acetyl aromatic esters instead of
methyl benzoates.
Chemoselectivity Cryptoregiochemistry Enantioselectivity Keto–enol
tautomerism Stereoselectivity...
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variations of the
Grignard reagent have been
discovered to
improve the
chemoselectivity of the
Grignard reaction,
which include but are not
limited to: Turbo-Grignards...
-
considerations to be made when
designing a
reductive amination reaction.
Chemoselectivity issues may
arise since the
carbonyl group is also reducible. The reaction...
- (1936). http://www.orgsynth.org/orgsyn/prep.asp?prep=cv2p0108 Link
Chemoselective Nitration of
Phenols with tert-Butyl
Nitrite in
Solution and on Solid...
- wide
range of
different types of
ketones in both a
stereoselective and
chemoselective manner.
Substrates include a
large variety of aryl-aliphatic, di-aliphatic...
