-
mostly occurs with low
melting point carbodiimides that are
liquids at room temperature.
Solid diaryl carbodiimides are more stable, but can
slowly undergo...
- for the
coupling of
primary amines to
yield amide bonds.
While other carbodiimides like
dicyclohexylcarbodiimide (DCC) or
diisopropylcarbodiimide (DIC)...
-
Inorganic carbodiimides (or
cyanamides depending on the NCN2- form)
design a
family of
compounds containing the
carbodiimide (or cyanamide)
anion NCN2-...
- and dimethylformamide, but
insoluble in water. The C−N=C=N−C core of
carbodiimides (N=C=N) is linear,
being related to the
structure of allene. The molecule...
-
particular couplings, many of
these reagents are
commercially available.
Carbodiimides such as
dicyclohexylcarbodiimide (DCC) and
diisopropylcarbodiimide (DIC)...
- is the
oxime of
ethyl cyanoacetate and
finds use as an
additive for
carbodiimides, such as
dicyclohexylcarbodiimide (DCC) in
peptide synthesis. It acts...
- bonding,
isocyanates are
closely related to
carbon dioxide (CO2) and
carbodiimides (C(NR)2). The C−N=C=O unit that
defines isocyanates is planar, and the...
- Ewa; Fiertek,
Dariusz (1994). "Reinvestigation of the
reactions of
carbodiimides with
alkoxycarbonylamino acid
symmetrical anhydrides:
Isolation of two...
- 1021/ja0057326. PMID 11414862. Ulrich,
Henri (2007).
Chemistry and
technology of
carbodiimides. Chichester, England: John
Wiley & Sons. ISBN 9780470065105....
- cyanamides.: 1392 As a
stabler valence isomer of
carbodiimides,
cyanamides form when
carbodiimides are
heated or
undergo electrophilic substitution.: 1393 ...
