- are
essentially synonymous with so-called 'non-classical
carbocations',
which are
carbocations that
contain bridging C–C or C–H σ-bonds. However, others...
-
became more widespread, however, higher-coordinate
carbocations were observed. Penta-coordinate
carbocations, also
described as
nonclassical ions,
cannot be...
-
reactivity of
carbocations via superacids. For this research, Olah was
awarded a
Nobel Prize in
Chemistry in 1994 "for his
contribution to
carbocation chemistry...
- and
related reactions and its
close relationship to the
discovery of
carbocations as intermediates. In a
simple demonstration reaction of 1,4-dimethoxybenzene...
-
alkylating agents (ones for
which carbocation rearrangement is degenerate), or
alkylating agents that
yield stabilized carbocations (e.g.,
benzylic or allylic...
- of the
corresponding carbocations.
Tertiary carbocations are far more
stable than
secondary carbocations, and
primary carbocations are the
least stable(due...
- isolated. Cations,
often carbocations,
serve as
intermediates in
various types of
reactions to
synthesize new compounds.
Carbocations are
formed in two major...
-
accurately described using steady-state kinetics. The
reaction involves a
carbocation intermediate and is
commonly seen in
reactions of
secondary or tertiary...
-
providing an
environment to create, maintain, and
characterize carbocations.
Carbocations are
intermediates in
numerous useful reactions such as
those forming...
- Rearrangement".
Organic Letters. 8 (25): 5793–6. doi:10.1021/ol062337x. PMID 17134274.. Markovnikov's rule and
carbocations – Khan Academy. 25
August 2010....
