-
trichloromethane (often
abbreviated as TCM), is an
organochloride with the
formula CHCl3 and a
common solvent. It is a volatile, colorless, sweet-smelling, dense...
- light. The
reaction is used for the
industrial synthesis of
chloroform (
CHCl3),
dichloromethane (CH2Cl2), and hexachlorobutadiene. It
proceeds by a free-radical...
-
solvent used in NMR spectroscopy. The
properties of CDCl3 and
ordinary CHCl3 (chloroform) are
virtually identical.
Deuterochloroform was
first made in...
-
acetyl groups into
carboxyl groups (R−C(=O)OH) or to
produce chloroform (
CHCl3), bro****rm (CHBr3), or
iodoform (CHI3). Note that
fluoroform (CHF3) can't...
- as an intermediate. CHCl 3 + 2 HF ⟶
CHClF 2 + 2 HCl {\displaystyle {\ce {
CHCl3 + 2 HF -> CHClF2 + 2 HCl}}} 2
CHClF 2 ⟶ C 2 F 4 + 2 HCl {\displaystyle {\ce...
- CH4 + Cl2 → CH3Cl + HCl CH3Cl + Cl2 → CH2Cl2 + HCl CH2Cl2 + Cl2 →
CHCl3 + HCl
CHCl3 + Cl2 → CCl4 + HCl The
output of
these processes is a
mixture of chloromethane...
- the
phase transfer catalyst benzyltriethylammonium chloride. Me3CNH2 +
CHCl3 + 3 NaOH → Me3CNC + 3 NaCl + 3 H2O
Similar reactions have been reported...
-
fluorination of
chloroform using a
catalyst such as
antimony trifluoride:
CHCl3 + HF → CHCl2F + HCl
Dichlorofluoromethane was used as a
propellant and refrigerant...
- ethoxide,
formed in-situ from
sodium and
absolute ethanol, and chloroform:
CHCl3 + 3 Na + 3 EtOH → HC(OEt)3 + 3⁄2 H2 + 3 NaCl
Triethyl orthoformate is used...
- solvents. The
reaction is
performed in
inert solvents (C6H14, C6H6, CH2Cl2,
CHCl3, CCl4)
between -10 and 60 °C with the
yield of 60-80%. An
illustrative example...
