- In chemistry, pi
backbonding or π
backbonding is a π-bonding
interaction between a
filled (or half filled)
orbital of a
transition metal atom and a vacant...
- low-spin
ferric [Fe(CN)6]3−,
since CN− is a
ligand that can have
backbonding.
While backbonding is
important in the
initial state, it
would only
warrant a small...
-
inorganic polymer, even
though they have
extensive organic substituents.
Their backbond is
composed of
alternating silicon and
oxygen atoms, i.e. Si-O-Si-O......
- (PhD) Known for See list
Alpha sheet Ancestral sequence reconstruction Backbonding Beta
sheet Bond
order Breath gas
analysis Coiled coil Corey-Pauling rules...
- than expected.
Aromatic interaction Delta bond
Molecular geometry Pi
backbonding Pi
interaction Streitwieser, Andrew; Heath****,
Clayton H.; Kosower,...
- backdonation. This
model is a
specific manifestation of the more
general π
backbonding model.
Similar to alkenes,
alkynes adopt a
similar bonding interaction...
- in
coordination complexes is metal-to-ligand π bonding, also
called π
backbonding. It
occurs when the
LUMOs (lowest
unoccupied molecular orbitals) of the...
-
decreases from 2143 cm−1 of free CO. This
shift can be
explained by π
backbonding: the
metal forms a π bond with the
carbonyl ligand by
donating electrons...
- of the
other lanthanides,
characterized by an
inability to
undergo π
backbonding. They are thus
mostly restricted to the
mostly ionic cyclopentadienides...
-
adding nucleophiles to a
species tetracoordinate at phosphorus.
Strongly backbonding Lewis acids (e.g.
tungsten pentacarbonyl) can
stabilize a
dative bond...
