-
effective in
aromatic decarboxylation: The
iconic complex in this
series is
allylpalladium chloride dimer (APC).
Allyl compounds with
suitable leaving groups react...
-
Allylpalladium(II)
chloride dimer (APC) is a
chemical compound with the
formula [(η3-C3H5)PdCl]2. This
yellow air-stable
compound is an
important catalyst...
-
compounds (for example, Zeise's salt), and η3-allyl
compounds (for example,
allylpalladium chloride dimer);
metallocenes containing cyclopentadienyl ligands (for...
-
presence of
catalytic Pd(OAc)2 and PPh3 via the
intermediacy of an
allylpalladium enolate - a
catalytic Carroll rearrangement.
Following work revealed...
- (CH2)2(CH=CH2)2 + MgCl2 It
undergoes oxidative addition to palladium(0) to give
allylpalladium chloride dimer, (C3H5)2Pd2Cl2.
Dehydrohalogenation gives cyclopropene...
- Allophycocyanin, a
protein from the light-harvesting
phycobiliprotein family Allylpalladium chloride dimer, a
chemical compound Ammonium perchlorate, a powerful...
-
including natural rubber. Transition-metal
allyl complexes, such as
allylpalladium chloride dimer Wikiquote has
quotations related to
Allyl group. Allylic...
-
Tsuji reported work that
confirmed his hypothesis. By
reacting an
allylpalladium chloride dimer with the
sodium salt of
diethyl malonate, the
group was...
-
Structure of
allylpalladium chloride dimer...
-
reaction is
initiated by the
elimination of
carbon dioxide to form π-
allylpalladium intermediate,
which is
followed by β-decarbopalladation to form dienals...
