-
carbanionic center, thus,
allyllithiums are
often less
aggregated than
alkyllithiums. In
aryllithium complexes, the
lithium cation coordinates to a single...
- "Preparation, Properties, and Safe
Handling of
Commercial Organolithiums:
Alkyllithiums,
Lithium sec-Organoamides, and
Lithium Alkoxides".
Organic Process Research...
-
plays an
important role in the
Grignard reaction.: 102 For example,
alkyllithiums and
aryllithiums may be used to
synthesise aldehydes and
ketones by...
-
Chemical class Structural formula Prefix Suffix Example Alkyllithium RLi (tri/di)alkyl- -lithium
methyllithium Alkylmagnesium halide RMgX (X=Cl, Br, I)[note...
- can be emplo****
without the
addition of a
metal hydride. The use of
alkyllithiums as
strong bases has not been
extensively studied, and have been unreliable...
- Lochmann-Schlosser base)
describes various superbasic mixtures of an
alkyllithium compound and a pot****ium alkoxide. The
reagent is
named after Manfred...
- such as [Ni(neocuproine)Cl2]2.
Alkyllithium reagents form
deeply colored derivatives with phenanthroline. The
alkyllithium content of
solutions can be determined...
- n-butyllithium: This
particular reaction requires the
interaction of the
alkyllithium group ortho to the
sulfone group akin a
directed ortho metalation. A...
- σ-vinylpalladium
complexes with
alkyllithiums.
Stereospecific syntheses of
olefins from
vinyl halides and
alkyllithiums".
Journal of
Organometallic Chemistry...
- Lithium–halogen
exchange is
frequently used to
prepare vinyl-, aryl- and
primary alkyllithium reagents.
Vinyl halides usually undergo lithium–halogen
exchange with...
