Definition of Agostic. Meaning of Agostic. Synonyms of Agostic

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Definition of Agostic

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Meaning of Agostic from wikipedia

- Agostic interaction is a term in organometallic chemistry for the interaction of a coordinatively-unsaturated transition metal with a C−H bond, when the...
- reaction of a Vaska's complex with methyl iodide. Some metal alkyls feature agostic interactions between a C-H bond on the alkyl group and the metal. Such...
- interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, and three-center two-electron bonds. The term...
- has been seen forming a coordination to lead in [2,4,6-(CF3)3C6H2]2Pb. Agostic interactions have also been shown to stabilize plumbylenes. DFT com****tions...
- complex via its carbonyl oxygen and agostically via its ortho C-H bond (2). As in the Ru0 proposed mechanism, this agostic interaction leads to the oxidative...
- A celebrated family of compounds featuring such interactions as called agostic complexes. This bonding pattern is also seen in trimethylaluminium, which...
- and his students synthesised several examples of complexes exhibiting "agostic" bonds. The word was suggested to him by Jasper Griffin, professor of Cl****ics...
- bonds in for example silanes, hydrocarbons, and dihydrogen (see also: Agostic interaction). In complexes of non-innocent ligands, the ligand is bonded...
- Co(norbornyl)4 (13 e−) [FeCp2]+ (17 e−) Sometimes such complexes engage in agostic interactions with the hydrocarbon framework of the bulky ligand. For example:...
- also follow a concerted mechanism through the formation of an M–(C–H) agostic complex. A representative example is the reaction of hydrogen with Vaska's...
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