- In
organometallic chemistry,
agostic interaction refers to the
intramolecular interaction of a coordinatively-unsaturated
transition metal with an appropriately...
- interactions,
including σ-bonding, π-bonding, metal-to-metal bonding,
agostic interactions, bent bonds, three-center two-electron
bonds and three-center...
- A
particularly common subset of
sigma complexes are
those featuring an
agostic interaction where a C–H σ-bond on one of its
ligands 'leans'
towards and...
-
reaction of a Vaska's
complex with
methyl iodide. Some
metal alkyls feature agostic interactions between a C-H bond on the
alkyl group and the metal. Such...
-
ligands extend to
include dihydrogen and
hydrocarbons that
interact by
agostic interactions. X
ligands are
halides and pseudohalides. X
ligands typically...
- metal-bonded
hydride and an alkene. Both α- and β-eliminations
proceed via
agostic intermediates.
Elimination reaction,
mainly focused on
organic substrates...
- non-coordinating
anions has
contributed to
increased understanding of
agostic complexes wherein hydrocarbons and
hydrogen serve as ligands. Non-coordinating...
- has been seen
forming a
coordination to lead in [2,4,6-(CF3)3C6H2]2Pb.
Agostic interactions have also been
shown to
stabilize plumbylenes. DFT com****tions...
- and his
students synthesised several examples of
complexes exhibiting "
agostic" bonds. The word was
suggested to him by
Jasper Griffin,
professor of classics...
- β-hydride
elimination than d2 and
higher metal alkyls and may form
isolable agostic complexes, even if an
empty coordination site is available. The S**** higher...
