- Agostic interaction
is a term in organometallic chemistry
for the interaction
of a coordinatively-unsaturated transition metal
with a C−H bond, when the...
of a Vaska's complex
iodide. Some metal alkyls feature agostic interactions between
a C-H bond on the alkyl group
and the metal. Such...
- interactions, including
σ-bonding, π-bonding, metal-to-metal bonding, agostic
interactions, bent bonds, three-center two-electron bonds
- has been seen forming
to lead in [2,4,6-(CF3)3C6H2]2Pb. Agostic interactions
have also been shown
plumbylenes. DFT com****tions...
in for example
silanes, hydrocarbons, and dihydrogen
(see also: Agostic
interaction). In complexes
of non-innocent ligands, the ligand
- non-coordinating anions
to increased understanding
of agostic complexes wherein hydrocarbons
and hydrogen serve
as ligands. Non-coordinating...
- A celebrated family
of compounds featuring
as called agostic
complexes. This bonding pattern
is also seen in trimethylaluminium, which...
from the fact that the clusters interact
interactions. In contrast
the bulkier cluster
- Co(norbornyl)4 (13 e−) [FeCp2]+ (17 e−) Sometimes
such complexes engage
in agostic interactions
with the hydrocarbon framework
of the bulky
ligand. For example:...
via its carbonyl oxygen
via its ortho
C-H bond (2). As in the Ru0 proposed
mechanism, this agostic interaction leads
to the oxidative...