- Agostic interaction
is a term in organometallic chemistry
for the interaction
of a coordinatively-unsaturated transition metal
with a C−H bond, when the...
- interactions, including
σ-bonding, π-bonding, metal-to-metal bonding, agostic
interactions, bent bonds, three-center two-electron bonds
of a Vaska's complex
iodide. Some metal alkyls feature agostic interactions between
a C-H bond on the alkyl group
and the metal. Such...
- has been seen forming
to lead in [2,4,6-(CF3)3C6H2]2Pb. Agostic interactions
have also been shown
plumbylenes. DFT com****tions...
in for example
silanes, hydrocarbons, and dihydrogen
(see also: Agostic
interaction). In complexes
of non-innocent ligands, the ligand
- and his students synthesised several examples
of complexes exhibiting
" bonds. The word was suggested
to him by Jasper
- non-coordinating anions
to increased understanding
of agostic complexes wherein hydrocarbons
and hydrogen serve
as ligands. Non-coordinating...
emplo**** to refer
to ligands containing extended
π-systems or where agostic bonding
is not obvious
from the formula. Ferrocene: bis(η5-cyclopentadienyl)iron...
D.; Wilson, Scott
R.; Girolami, Gregory
S. (1994). "A Static Agostic
α-CH-M Interaction Observable
by NMR Spectroscopy: Synthesis
of the Chromium(II)...
via its carbonyl oxygen
via its ortho
C-H bond (2). As in the Ru0 proposed
mechanism, this agostic interaction leads
to the oxidative...