Definition of Agostic. Meaning of Agostic. Synonyms of Agostic

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Definition of Agostic

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Meaning of Agostic from wikipedia

- Agostic interaction is a term in organometallic chemistry for the interaction of a coordinatively-unsaturated transition metal with a C−H bond, when the...
- reaction of a Vaska's complex with methyl iodide. Some metal alkyls feature agostic interactions between a C-H bond on the alkyl group and the metal. Such...
- interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron bonds and three-center...
- has been seen forming a coordination to lead in [2,4,6-(CF3)3C6H2]2Pb. Agostic interactions have also been shown to stabilize plumbylenes. DFT com****tions...
- bonds in for example silanes, hydrocarbons, and dihydrogen (see also: Agostic interaction). In complexes of non-innocent ligands, the ligand is bonded...
- non-coordinating anions has contributed to increased understanding of agostic complexes wherein hydrocarbons and hydrogen serve as ligands. Non-coordinating...
- A celebrated family of compounds featuring such interactions as called agostic complexes. This bonding pattern is also seen in trimethylaluminium, which...
- results from the fact that the clusters interact via further inter-cluster agostic interactions. In contrast the bulkier cluster (tertiary-butylLi)4, where...
- Co(norbornyl)4 (13 e−) [FeCp2]+ (17 e−) Sometimes such complexes engage in agostic interactions with the hydrocarbon framework of the bulky ligand. For example:...
- complex via its carbonyl oxygen and agostically via its ortho C-H bond (2). As in the Ru0 proposed mechanism, this agostic interaction leads to the oxidative...
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