- Agostic interaction
is a term in organometallic chemistry
for the interaction
of a coordinatively-unsaturated transition metal
with a C−H bond, when the...
of a Vaska's complex
iodide. Some metal alkyls feature agostic interactions between
a C-H bond on the alkyl group
and the metal. Such...
- interactions, including
σ-bonding, π-bonding, metal-to-metal bonding, agostic
interactions, bent bonds, and three-center two-electron bonds. The term...
- has been seen forming
to lead in [2,4,6-(CF3)3C6H2]2Pb. Agostic interactions
have also been shown
plumbylenes. DFT com****tions...
via its carbonyl oxygen
via its ortho
C-H bond (2). As in the Ru0 proposed
mechanism, this agostic interaction leads
to the oxidative...
- A celebrated family
of compounds featuring
as called agostic
complexes. This bonding pattern
is also seen in trimethylaluminium, which...
- and his students synthesised several examples
of complexes exhibiting
" bonds. The word was suggested
to him by Jasper
in for example
silanes, hydrocarbons, and dihydrogen
(see also: Agostic
interaction). In complexes
of non-innocent ligands, the ligand
- Co(norbornyl)4 (13 e−) [FeCp2]+ (17 e−) Sometimes
such complexes engage
in agostic interactions
with the hydrocarbon framework
of the bulky
ligand. For example:...
- also follow
a concerted mechanism through
of an M–(C–H) agostic
complex. A representative example
is the reaction