- trans-
vinylcyclopropanes tend to form more of the symmetry-allowed ar- and si-cyclopentenes
supportive of a
concerted mechanism, the cis-
vinylcyclopropanes...
- are
relatively rare, but
still feasible in
certain cases. However,
vinylcyclopropanes readily undergo formal [5+2]
processes catalyzed by
transition metal...
- 15227/orgsyn.019.0036. Baldwin, John E. (2003). "Thermal
Rearrangements of
Vinylcyclopropanes to Cyclopentenes".
Chemical Reviews. 103 (4): 1197–212. doi:10.1021/cr010020z...
-
addition to the
distal C-C bond can isomerize.
Oxidative addition of
vinylcyclopropanes primarily occurs at the
proximal position,
giving pi-allyl intermediates...
- CAS 30334-81-7
Cyclopropane derivatives:
Ethenylcyclopropane or
Vinylcyclopropane Ethylidenecyclopropane, CAS 18631-83-9 2-Methyl-1-methylenecyclopropane...
-
cyclopropyl ring or the substituents.
Vinylcyclopropanes are a
special case as they
undergo vinylcyclopropane rearrangement.
Cyclopropane derivatives...
-
stimulation causes 1,4-dienes to
rearrange to form
vinylcyclopropanes.
These can then
undergo vinylcyclopropane rearrangements Cyclopropane-fatty-acyl-phospholipid...
- catalyst. This can be
considered similar to the ring
expansion seen in
vinylcyclopropane rearrangements Substituted methylenecyclopropanes can also be involved...
-
Transition Metal-Catalyzed [5 + 2]
Cycloadditions of
Allenes and
Vinylcyclopropanes:
First Studies of Endo-Exo Selectivity, Chemoselectivity, Relative...
-
Ingelheim chemists were able to
shift the site of
initiation from the
vinylcyclopropane moiety to the
nonenoic acid moiety,
improving the rate of the intramolecular...
