-
wherein the net
result is one σ-bond is
changed to
another σ-bond in an
uncatalyzed intramolecular reaction. The name
sigmatropic is the
result of a compounding...
-
convert to
carbonic acid,
remaining dissolved CO2 gas. However, the
uncatalyzed equilibrium is
reached quite slowly: the rate
constants are 0.039 s−1...
- In chemistry, a
phosphaalkyne (IUPAC name: alkylidynephosphane) is an
organophosphorus compound containing a
triple bond
between phosphorus and carbon...
-
catalytic rate of
chemical reactions up to 100,000,000,000-fold over the
uncatalyzed reaction. The most
extensively studied class of
DNAzymes is RNA-cleaving...
- (Mar 1988-1992) - 4A-FE petrol,
uncatalyzed, 94 bhp (70 kW; 95 PS) 1.6 XL (Apr 1990-1992) - 4A-FE petrol,
uncatalyzed, 94 bhp (70 kW; 95 PS) 2.0 GL Executive...
- PMC 3366509. PMID 17051221.
Radzicka A,
Wolfenden R (July 1996). "Rates of
Uncatalyzed Peptide Bond
Hydrolysis in
Neutral Solution and the
Transition State...
- of Ea‡ (when the
system is
already in the ES‡)
relative to Ea‡ in the
uncatalyzed reaction in
water (without the enzyme). The
induced fit only suggests...
-
decarboxylation reaction catalyzed by the
enzyme orotidylate decarboxylase.
Uncatalyzed, the
decarboxylation reaction is
extremely slow (estimated to
occur on...
-
charged repulsion.
Extrapolating from
known fusion rates, the rate for
uncatalyzed fusion at room-temperature
energy would be 50
orders of
magnitude lower...
-
transition state such that it
requires less
energy to
achieve compared to the
uncatalyzed reaction (ES‡).
Finally the enzyme-product
complex (EP)
dissociates to...
