-
cyclic thiosulfinates containing the 1,2-dithiolane-1-oxide ring,
isolated from the
tropical weed
Sphenoclea zeylanica.
These heterocyclic thiosulfinates are...
-
compounds serve as the
precursors of
several thiosulfinates such as S-(2-hydroxyethyl) 2-hydroxyethane)
thiosulfinate, S-(2-hydroxylethyl) phenylmethanethiosulfinate...
- ("sulfide oxide"), a sulfone, R−S(O)2−R, is the S,S-dioxide of a sulfide, a
thiosulfinate, R−S(O)−S−R, is the S-oxide of a disulfide, and a thiosulfonate, R−S(O)2−S−R...
-
which is
responsible for the
aroma of
fresh garlic.
Allicin and
other thiosulfinates in
garlic are
unstable and form a
number of
other compounds, such as...
- to
chemical substances.
Substances such as piperine, capsaicin, and
thiosulfinates can
cause a
burning or
tingling sensation by
inducing a
trigeminal nerve...
-
lachrymatory agent (Z)-butanethial S-oxide,
along with
several 1-butenyl
thiosulfinates are
detected by m****
spectrometry using a DART ion source. (Z)-Butanethial...
- well as
oxidation with
hydrogen peroxide or
peracetic acid
giving the
thiosulfinate compound,
methyl methanethiosulfinate (CH3S(O)SCH3). DMDS is used as...
-
ester through a 6-membered
cyclic transition state yields the alkene.
Thiosulfinates can
eliminate in the
manner analogous to sulfoxides. Representative...
- Cl2 -> 2 ArSCl}}} More unusually,
oxidation of
disulfides gives first thiosulfinates and then thiosulfonates: RSSR + [O] → RS(=O)SR RS(=O)SR + [O] → RS(=O)2SR...
-
sufinyl derivatives such as sulfinamides, sulfinates, sulfoxides, and
thiosulfinates.
Unlike the
sulfur atom in
sulfonyl halides and
sulfenyl halides, the...
