- In
organosulfur chemistry,
thiosulfinate is a
functional group consisting of the
linkage R-S(O)-S-R (R are
organic substituents).
Thiolsulfinates are...
- odor. It is a
thioester of
sulfenic acid. It is also
known as
allyl thiosulfinate. Its
biological activity can be
attributed to both its
antioxidant activity...
- well as
oxidation with
hydrogen peroxide or
peracetic acid
giving the
thiosulfinate methyl methanethiosulfinate (CH3S(O)SCH3). DMDS is used as a food additive...
-
compounds serve as the
precursors of
several thiosulfinates such as S-(2-hydroxyethyl) 2-hydroxyethane)
thiosulfinate, S-(2-hydroxylethyl) phenylmethanethiosulfinate...
-
ester through a 6-membered
cyclic transition state yields the alkene.
Thiosulfinates can
eliminate in the
manner analogous to sulfoxides. Representative...
-
Phosphaallene Sulfur Thiol Sulfide Sulfonium Persulfide Disulfide Sulfenic acid
Thiosulfinate Sulfoxide Thiosulfonate Sulfinic acid
Sulfone Sulfonic acid Thioketone...
- Cl2 -> 2 ArSCl}}} More unusually,
oxidation of
disulfides gives first thiosulfinates and then thiosulfonates: RSSR + [O] → RS(=O)SR RS(=O)SR + [O] → RS(=O)2SR...
-
Phosphaallene Sulfur Thiol Sulfide Sulfonium Persulfide Disulfide Sulfenic acid
Thiosulfinate Sulfoxide Thiosulfonate Sulfinic acid
Sulfone Sulfonic acid Thioketone...
- to
cleave the sulfur-containing
compound alliin to
release reactive thiosulfinates.
These then
react with each
other and with
amino acids found naturally...
- ("sulfide oxide"), a sulfone, R−S(O)2−R, is the S,S-dioxide of a sulfide, a
thiosulfinate, R−S(O)−S−R, is the S-oxide of a disulfide, and a thiosulfonate, R−S(O)2−S−R...
