Definition of Thiocarbonyldiimidazole. Meaning of Thiocarbonyldiimidazole. Synonyms of Thiocarbonyldiimidazole

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Definition of Thiocarbonyldiimidazole

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Meaning of Thiocarbonyldiimidazole from wikipedia

- 1,1'-Thiocarbonyldiimidazole (TCDI) is a thiourea containing two imidazole rings. It is the sulfur analog of the peptide coupling reagent carbonyldiimidazole...
- the American-Estonian chemist Roland Arthur Edwin Winter. Often, thiocarbonyldiimidazole is used instead of thiophosgene as shown above, since thiophosgene...
- transformation of 1,2-diols to alkenes involving the diol substrate, thiocarbonyldiimidazole, and excess trialkylphosphite. The exact mechanism is unknown,...
- selectivity: it allows the synthesis of asymmetric bis alkyl carbonates Thiocarbonyldiimidazole (TCDI) the thiourea analogue H.A. Staab (1962). "Syntheses Using...
- azadirachtin: In another variation the reagent is the imidazole 1,1'-thiocarbonyldiimidazole (TCDI), for example in the total synthesis of pallescensin B. TCDI...
- combined elimination reaction and Barton deoxygenation with 1,1'-thiocarbonyldiimidazole forming alkene 42. Finally the C15 hydroxyl group was introduced...