Definition of TMEDA. Meaning of TMEDA. Synonyms of TMEDA

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Definition of TMEDA

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Meaning of TMEDA from wikipedia

- Tetramethylethylenediamine (TMEDA or TEMED) is a chemical compound with the formula (CH3)2NCH2CH2N(CH3)2. This species is derived from ethylenediamine...
- is around 11 kcal/mol. TMEDA can also chelate to the lithium cations in n-butyllithium and form solvated dimers such as [(TMEDA) LiBu-n)]2. Phenyllithium...
- of which is dilithioferrocene. Fe(C5H5)2 + 2 LiC4H9 + 2 TMEDA → 2 C4H10 + Fe(C5H4Li)2(TMEDA)2 Schlosser's base is a superbase produced by treating butyllithium...
- reaction with tetramethylethylenediamine (tmeda): [Ni(CH3COCHCOCH3)2]3 + 3 tmeda → 3 Ni(CH3COCHCOCH3)2(tmeda) Ni(acac)2(H2O)2 reacts quickly in high yield...
- this reaction sequence the R–Pd(II)–Br starting complex 1 stabilized by TMEDA is converted through dppe to metal complex 2. Electrophilic attack of methyl...
- dibutyl magnesium in ether or hydrocarbon solvents in the presence of THF or TMEDA as ligand. The room temperature form α-MgH2 has a rutile structure. There...
- like dimethoxyethane (DME) or ligands like tetramethylethylenediamine (TMEDA). As an exception to the duet rule, a two-coordinate lithate complex with...
- trans-(PCy2Ph)2Ni(o-tolyl)Cl]], (dppf)Ni(o-tolyl)Cl]], (TMEDA)Ni(o-tolyl)Cl, and (TMEDA)NiMe2, (TMEDA)Ni(Br)(C6F5).[1] Nickel compounds of the type NiR2 also...
- complexes. It is prepared from the tmeda adduct of nickel(II) acetylacetonate by reaction with methyl lithium. The tmeda ligand is easily displaced by bases...
- [Th(CH3)7]3−, heptamethylthorate(IV), which forms the salt [Li(tmeda)]3[Th(CH3)7] (tmeda = (CH3)2NCH2CH2N(CH3)2). Although one methyl group is only attached...