- intermediate.
Alkylation of
sulfinic acids can give
either sulfones or
sulfinate esters,
depending on the
solvent and reagent.
Strongly polarized reactants...
-
names in
common use
include cysteine-
sulfinate decarboxylase, L-cysteinesulfinic acid decarboxylase, cysteine-
sulfinate decarboxylase, CADCase/CSADCase, CSAD...
- microalgae. By contrast, most
taurine in
animals is made from
cysteine sulfinate. Weast,
Robert C., ed. (1981). CRC
Handbook of
Chemistry and
Physics (62nd ed...
-
Sulfones have been
prepared by
nucleophilic displacement of
halides by
sulfinates: ArSO 2 Na + Ar ′ Cl ⟶ Ar ( Ar ′ ) SO 2 + NaCl {\displaystyle {\ce {ArSO2Na...
-
unusual reaction focusing on the
sulfur center, zinc
reduces TsCl to the
sulfinate, CH3C6H4SO2Na. This
reagent is
inexpensively available for laboratory...
-
catalyzes the
conversion of L-cysteine to
cysteine sulfinic acid (cysteine
sulfinate). CDO
plays an
important role in
cysteine catabolism,
regulating intracellular...
- fish are less
efficient at
taurine biosyntheis due to
reduced cysteine sulfinate decarboxylase levels.
Taurine is used in the
preparation of the anthelmintic...
-
menthol is used as a
chiral auxiliary in
asymmetric synthesis. For example,
sulfinate esters made from
sulfinyl chlorides and
menthol can be used to make enantiomerically...
-
section are too
loosely tied to the text, e.g.,
there is no
mention of
sulfinate ester or
imine hydrolysis,
though this is what the
schemes present, and...
-
delivery occurs to give
intermediate 5,
followed by
elimination of the
metal sulfinate to give azo
intermediate 6. This
intermediate then decomposes, with loss...
