-
group is
proposed as the
nucleophile that
attacks the nitrile. The
prefix sulfenyl in
organic nomenclature denotes the RS
group (R ≠ H). One
example is methanesulfenyl...
-
organosulfur chemistry, a
sulfenyl chloride is a
functional group with the
connectivity R−S−Cl,
where R is
alkyl or aryl.
Sulfenyl chlorides are reactive...
-
Trichloromethane sulfenyl chloride or
perchloromethyl mercaptan is the
organosulfur compound with the
formula Cl3C−S−Cl. It is
mainly used as an intermediate...
-
where X is a halogen. They are
intermediate in
oxidation level between sulfenyl halides, R−S−X, and
sulfonyl halides, R−SO2−X. The best
known examples...
- the
chemical formulas that follow)
bonded to a
single sulfur atom, e.g.:
sulfenyl halides, RSX;
sulfinyl halides, RS(O)X;
sulfonyl halides, RSO2X; alkyl...
-
sulfonamides (RS(O)2NR2).
Sulfenamides are
usually prepared by the
reaction of
sulfenyl chlorides and amines: RSCl + R'2NH → RSNR'2 + HCl The S-N bond formation...
- ("addition, electrophilic, second-order").
Iodine (I2),
chlorine (Cl2),
sulfenyl ion (RS+),
mercury cation (Hg2+), and
dichlorocarbene (:CCl2) also react...
- of
protein thiols. In
Zincke cleavage,
halogens oxidize disulfides to a
sulfenyl halide:
ArSSAr + Cl 2 ⟶ 2
ArSCl {\displaystyle {\ce {ArSSAr + Cl2 -> 2...
-
oxygen (one element, not C, H or O)
Other Isothiocyanate Phosphoramides Sulfenyl chloride Sulfonamide Thiocyanate Sulfinylamines See also
chemical classification...
-
radical can
dissociate from the halogen. Thus, for example, sulfonyl,
sulfenyl, and
other sulfur halides can add
radically to give
respectively β‑halo...
