- not
until after the
observations of
certain molecular phenomena that
stereochemical principles were developed. In 1815, Jean-Baptiste Biot's observation...
- 1002/anie.200300626. PMID 14694470.
Short Synthesis of
Skeletally and
Stereochemically Diverse Small Molecules by
Coupling Petasis Condensation Reactions...
- Bennett, M. J.; Jones, C. E.; Smith, R. A.; Graham, W. A. G. (1977). "
Stereochemically Nonrigid Six-Coordinate
Metal Carbonyl Complexes. 1.
Polytopal Rearrangement...
- 1021/ja00045a027.
Ralph A.
Wheeler and P. N. V.
Pavan Kumar (1992). "
Stereochemically active or
inactive lone pair
electrons in some six-coordinate, group...
-
original structure. If present, the
stereochemical layer, with
sublayers b, /t, /m and /s,
gives stereochemical information, and the
isotopic layer /i...
-
shorter and two longer. The
pyramidal nature indicates the
presence of a
stereochemically active lone pair of electrons. When PbO
occurs in
tetragonal lattice...
- no
ionic intermediate. In
contrast to the E1 eliminations,
different stereochemical configurations are
possible for the
reaction product in the E2 mechanism...
-
apart from
achiral glycine, but also (3R) at the β-carbon. The full
stereochemical specification is (2S,3R)-L-threonine.
Nonpolar amino acid interactions...
- The
geometry is
common for
certain main
group compounds that have a
stereochemically-active lone pair, as
described by
VSEPR theory.
Certain compounds crystallize...
-
advancements in
synthetic methodology,
chemists have been able
synthesize stereochemically selective complex molecules without racemization.
Stereocontrol provides...
