- In
organophosphorus chemistry,
phosphoramidates (sometimes also
called amidophosphates) are a
class of
phosphorus compounds structurally related to phosphates...
-
approach was made in 1992, when the
efficiency of
aryloxy phosphates and
phosphoramidates was noted. In particular,
diaryl phosphates were
prepared from zidovudine...
- enzymology, a
phosphoramidate-hexose
phosphotransferase (EC 2.7.1.62) is an
enzyme that
catalyzes the
chemical reaction phosphoramidate +
hexose ⇌ {\displaystyle...
-
oxidized by CCl4 in the
presence of
primary or
secondary amines to
phosphoramidate analogs 12. The
method is very
convenient in that
various types of...
-
phosphoester bond formation, on histidine,
lysine and
arginine through phosphoramidate bonds, and on
aspartic acid and
glutamic acid
through mixed anhydride...
- as
competitive inhibitors of an
enzymatic reaction. An
example is
phosphoramidate to the
Tetrahymena group I ribozyme.
Other examples of
substrate analogs...
-
adenylyl sulfate + NH3 ⇌ {\displaystyle \rightleftharpoons }
adenosine 5'-
phosphoramidate + sulfate. Thus, the two
substrates of this
enzyme are
adenylyl sulfate...
-
bound to a
nitrogen atom in an
imidazole ring. They are a type of
phosphoramidate.
These phosphorus (V)
compounds are
encountered as
reagents used for...
-
enzymes cathepsin A or
carboxylesterase 1,
followed by
cleaving of the
phosphoramidate by the
enzyme histidine triad nucleotide-binding
protein 1 (HINT1)...
- an
asymmetric copper-catalysed
addition of
dialkylzincs to enones.
Phosphoramidate Teichert, J.; Feringa, B. (2010). "Phosphoramidites:
Privileged Ligands...