- CH3OH → (CH3O)2PPh + 2 HCl
Oxidation of
phosphonites gives phosphonates: 2 P(OR)2R + O2 → 2 OP(OR)2R
Phosphonites can
function as
ligands in homogeneous...
-
Arbuzov reaction;
phosphite esters (1)
react to form
phosphonates (2),
phosphonites (3)
react to form
phosphinates (4) and
phosphinites (5)
react to form...
-
organometallic chemistry.
Intermediate between phosphites and
phosphines are
phosphonites (P(OR)2R') and
phosphinite (P(OR)R'2). Such
species arise via alcoholysis...
- are
amenable to
asymmetrically hydrogenation with
cationic rhodium(I)
phosphonite systems, and I2 and
acetic acid
system with ee
values usually above 90%...
- VX. It is a
sulfide of the
chemical QL, or
isopropyl aminoethylmethyl phosphonite. QL
sulfide is
manufactured by
reacting QL with sulfur. QL
sulfide is...
- ISBN 0-444-89307-5. Rajanbabu, T. V. Babu (2012). "Phosphinite and
Phosphonite Ligands". Phosphorus(III)
Ligands in
Homogeneous Catalysis:
Design and...
-
Isopropyl aminoethylmethyl phosphonite (NATO
designation QL), also
known as O-(2-diisopropylaminoethyl) O′-ethyl methylphosphonite, is a
precursor chemical...
-
transesterified with N,N-diisopropylaminoethanol to
produce QL, a
mixed phosphonite. Finally, this
immediate precursor is
reacted with
sulfur to form VX...
- O-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl
alkyl (Me, Et, n-Pr or i-Pr)
phosphonites and
corresponding alkylated or
protonated salts, e.g. QL: O-Ethyl...
- alkenes.
Related complexes are
known for
phosphinites (R2P(OR')) and
phosphonites (RP(OR')2). Due to the
chelate effect,
ligands with two
phosphine groups...
