- pH it
converts to
sodium decavanadate. It is also
precursor to
exotic metalates such as [γ-PV2W10O40]5-, [α-PVW11O40]4-, and [β-PV2W10O40]5-.
Sodium metavanadate...
- single-electron-transfer
mechanism of the type
shown below.
Magnesium similarly metalates organohalides to give
Grignard reagents. Frankland, E. (1849). "Ueber...
-
metalation is an
important class of
metalation reactions.
Metalated sulfones, acyl
groups and α-
metalated amides are
important intermediates in
chemistry synthesis...
- The
higher alkali metals are
known to
metalate even some
unactivated hydrocarbons and are
known to self-
metalate: 2 NaC2H5 → C2H4Na2 + C2H6 In the ****lyn...
-
Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to
several atoms or
small groups. Look up
metallate in Wiktionary...
- base with an
electrophile such as
iodomethane gives N-methylpyrrole. N-
Metalated pyrrole can
react with
electrophiles at the N or C positions, depending...
- t-Butyllithium and s-butyllithium are more basic. n-BuLi can
deprotonate (that is,
metalate) many
types of C−H bonds,
especially where the
conjugate base is stabilized...
- ISBN 978-0-471-26418-7. Yang, Xun; Fleming,
Fraser F. (2017). "C- and N-
Metalated Nitriles: The
Relationship between Structure and Selectivity". Accounts...
-
Other supernucleophilic metal centers include low
oxidation state carbonyl metalate anions (e.g., CpFe(CO)2–). The
following table shows the nucleophilicity...
-
species of the type R2P(CH2)nPR2
where n >4 and R = tert-butyl.
Platinum metalates one
methylene group with
release of HCl,
giving species such as...
