-
labilization of
ligand dissociation. 3.
Survey of
group 6 and 7 six-coordinate
carbonyl compounds. The site
preference model for
ligand labilization effects"...
-
example is the cis
effect in
organometallic chemistry,
which is the
labilization of CO
ligands in the cis
position of
octahedral transition metal complexes...
- chemistry. This
pathway can be well
described by the cis effect, or the
labilization of CO
ligands in the cis position.
Complexes that
undergo dissociative...
- systems.
Other ligands have weak π-backbonding abilities,
which creates a
labilization effect of CO,
which is
described by the cis effect. As in metal–carbonyls...
- chemistry. This
pathway can be well
described by the cis effect, or the
labilization of CO
ligands in the cis position. The
opposite pathway is ****ociative...
-
Hieber is also
known for his work with the cis effect, also
known as the
labilization of CO
ligands in the cis
position in
octahedral complexes.
Hieber was...
-
Borisevich is best
known for his 1955
discovery of the
stabilization and
labilization phenomenon of
electronically excited polyatomic molecules, but also developed...
- co-****embly", "kinetic
analysis and tuning", "linker installation", "linker
labilization", "cluster and
linker metalation", "linker migration", "domino lattice...
- also
induced by NaOH or NaBH4. The
catalyst attacks a CO ligand,
which labilizes another CO
ligand toward substitution. The
electrophilicity of Fe(CO)4L...
- well as
group 7) are also well
known for
exhibiting the cis
effect (the
labilization of CO in the cis position) in
organometallic synthesis.
Group 7 elements...
