-
labilization of
ligand dissociation. 3.
Survey of
group 6 and 7 six-coordinate
carbonyl compounds. The site
preference model for
ligand labilization effects"...
-
example is the cis
effect in
organometallic chemistry,
which is the
labilization of CO
ligands in the cis
position of
octahedral transition metal complexes...
- chemistry. This
pathway can be well
described by the cis effect, or the
labilization of CO
ligands in the cis position.
Complexes that
undergo dissociative...
- This
electron donation is also
exhibited with the cis effect, or the
labilization of CO
ligands in the cis position.
Nickel carbonyl, for example, forms...
- systems.
Other ligands have weak π-backbonding abilities,
which creates a
labilization effect of CO,
which is
described by the cis effect. As in metal–carbonyls...
-
degrades proteins (e.g., food).
Peptide bonds,
which comprise proteins, are
labilized. The
gastric chief cells of the
stomach secrete enzymes for
protein breakdown...
- also
induced by NaOH or NaBH4. The
catalyst attacks a CO ligand,
which labilizes another CO
ligand toward substitution. The
electrophilicity of Fe(CO)4L...
- chemistry. This
pathway can be well
described by the cis effect, or the
labilization of CO
ligands in the cis position. The
opposite pathway is ****ociative...
- 366 nm
light is slow,
while using a 355 nm
pulsed laser results in
faster labilization of NS.
Evidence suggests that NS can
react with
itself to
reach N2S2...
-
Borisevich is best
known for his 1955
discovery of the
stabilization and
labilization phenomenon of
electronically excited polyatomic molecules, but also developed...
