- In
organometallic chemistry, the
isolobal principle (more
formally known as the
isolobal analogy) is a
strategy used to
relate the
structure of organic...
- a
benzene ring in
which two of the C-H
fragments have been
replaced by
isolobal nitrogen.
There are
three structural isomers:
pyridazine (1,2-diazine)...
- the same
number of
electrons but they do not have the same structure.
Isolobal principle IUPAC,
Compendium of
Chemical Terminology, 2nd ed. (the "Gold...
- is
isolobal,
hence the
rules are
applicable to carboranes. This can be
explained due to a
frontier orbital treatment.
Additionally there are
isolobal transition-metal...
-
dimanganese decacarbonyl is
formed in
terms of the
isolobal analogy of two d7 Mn(CO)5 fragments, that are
isolobal to the
methyl radical CH• 3. In
analogy to...
- 1965
prize for
other work.) In his
Nobel Lecture,
Hoffmann introduced the
isolobal analogy for
predicting the
bonding properties of
organometallic compounds...
- metal-metal bond also
often occurs. The d9-ML3
fragment Co(CO)3
fragment is
isolobal with methylidyne, CH.
Though there are
differences in the a1 and e energies...
-
organometallic compounds is
often discussed from the
perspective of the
isolobal principle. A wide
variety of
physical techniques are used to determine...
- d-electron count, the 18-electron rule,
oxidation state, valency, and the
isolobal analogy. Many
procedures have been
reported for the
synthesis of Mn2(CO)10...
-
system with two more electrons,
making the
cyclopropyl methyl cation's HOMO
isolobal to the
allyl anion's HOMO. Jung,
Sebastian T.; Nickisch, Roman; Reinsperger...
