- In
organometallic chemistry, the
isolobal principle (more
formally known as the
isolobal analogy) is a
strategy used to
relate the
structure of organic...
- was soon
understood by many
organometallic chemists that a Cp
ligand is
isolobal to Tp. As many
insights into
chemistry can be
obtained by the
study of...
- is
isolobal,
hence the
rules are
applicable to carboranes. This can be
explained due to a
frontier orbital treatment.
Additionally there are
isolobal transition-metal...
- a
benzene ring in
which two of the C-H
fragments have been
replaced by
isolobal nitrogen.
There are
three structural isomers:
pyridazine (1,2-diazine)...
-
system with two more electrons,
making the
cyclopropyl methyl cation's HOMO
isolobal to the
allyl anion's HOMO. Jung,
Sebastian T.; Nickisch, Roman; Reinsperger...
- the same
number of
electrons but they do not have the same structure.
Isolobal principle IUPAC,
Compendium of
Chemical Terminology, 2nd ed. (the "Gold...
- 1965
prize for
other work.) In his
Nobel Lecture,
Hoffmann introduced the
isolobal analogy for
predicting the
bonding properties of
organometallic compounds...
-
dimanganese decacarbonyl is
formed in
terms of the
isolobal analogy of two d7 Mn(CO)5 fragments, that are
isolobal to the
methyl radical CH• 3. In
analogy to...
-
hence these complexes are
referred to as π-complexes. η5-coordinated Cp is
isolobal to
three facial carbonyls, as well as
scorpionate ligands and thia-crown...
- of the
hydrogen or
substituent on the carbon—the
overall replacement is
isolobal. 6-membered
rings with one
nitrogen atom:
pyridines 6-membered
rings with...
