Definition of Hexamethyldisilane. Meaning of Hexamethyldisilane. Synonyms of Hexamethyldisilane

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Definition of Hexamethyldisilane

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Meaning of Hexamethyldisilane from wikipedia

- Hexamethyldisilane (TMS2) is the organosilicon compound with the formula Si2(CH3)6, abbreviated Si2Me6. It is a colourless liquid, soluble in organic solvents...
- analogous couplings are useful for coupling main group halides. Hexamethyldisilane arises efficiently by treatment of trimethylsilyl chloride with sodium:...
- tetrabromide Silicon tetrachloride Silicon tetrafluoride Silicon tetraiodide Hexamethyldisilane Related compounds Neopentane Tetramethylgermane Tetramethyltin Tetramethyllead...
- give tricyclic pyrroles. Reduction of trimethylsilyl chloride give hexamethyldisilane: 2 Me 3 SiCl + 2 Na ⟶ 2 NaCl + Me 3 Si − SiMe 3 {\displaystyle {\ce...
- the related silylmetalation, a metal replaces the hydrogen atom. Hexamethyldisilane reacts with methyl lithium to give trimethylsilyl lithium: (CH3)6Si2...
- Trimethylsilyl iodide may be prepared by the oxidative cleavage of hexamethyldisilane by iodine or by the cleavage of hexamethyldisiloxane with aluminium...
- RCONR'2 + Litms → RC(O)tms + LiNR'2 Acid chlorides are converted using hexamethyldisilane: RCOCl + tms−tms → RC(O)tms + tmsCl Some acyl silanes are prepared...
- Main hazards Extremely flammable Related compounds Related disilanes Hexamethyldisilane Related compounds Ethane Digermane Except where otherwise noted, data...
- when stood under light as an ethereal solution, it decomposes to hexamethyldisilane: TMS2Hg → (CH3)3Si-Si(CH3)3 + Hg Reaction with hydrogen chloride gives...