- of the R and S enantiomers. In 2001,
David E.
Nichols reported an
enantiospecific synthesis of Bromo-DragonFLY
which allowed the
individual R and S enantiomers...
-
constant for ethanol. Thus,
after only a few
percent solvolysis of an
enantiospecific substrate, it
becomes racemic. The
examples in
textbooks of secondary...
-
simplest molecule to
exhibit enantiomerism. It has been
proposed that the
enantiospecific interactions of one
rather than the
other may have led to amplification...
- Zhou, Hao; Liao, Xuebin; Cook,
James M. (2004-01-01). "Regiospecific,
Enantiospecific Total Synthesis of the 12-Alkoxy-Substituted
Indole Alkaloids,...
- 1002/14356007.a11_141 Srikrishna, A.;
Jagadeeswar Reddy, T. (1998). "
Enantiospecific synthesis of (+)-(1S, 2R, 6S)-1, 2-dimethylbicyclo [4.3. 0] nonan-8-one...
- of the
thiophenyl group to give the
sulfoxide as
below proceeded enantiospecifically due to the
predefined stereochemistry of the
propargylic alcohol...
- own
specific way.
Stereospecificity towards enantiomers is
called enantiospecificity.
Nucleophilic substitution at sp3
centres can
proceed by the stereospecific...
-
Chambers JJ, Kurrasch-Orbaugh DM,
Parker MA,
Nichols DE (March 2001). "
Enantiospecific synthesis and
pharmacological evaluation of a
series of super-potent...
-
dihydroxylation of
olefins using osmium tetraoxide clarifies the
origin of
enantiospecificity". J. Am. Chem. Soc. 26 (115): 12579. doi:10.1021/ja00079a045. Kolb...
-
Chambers JJ, Kurrasch-Orbaugh DM,
Parker MA,
Nichols DE (March 2001). "
Enantiospecific synthesis and
pharmacological evaluation of a
series of super-potent...
