-
Trimethylsilyl chloride, also
known as
chlorotrimethylsilane is an
organosilicon compound (silyl halide), with the
formula (CH3)3SiCl,
often abbreviated...
-
Jordan J.; Nelke,
Janice M. (1977). "Acyloin
Condensation in
Which Chlorotrimethylsilane is Used as a
Trapping Agent: 1,2-Bis(Trimethylsilyloxy)Cyclobutene...
- G. Balaram; Malhotra,
Ripudaman (1979). "Transformations with
chlorotrimethylsilane/sodium iodide, a
convenient in situ
Iodotrimethylsilane Reagent"...
- ((SiMe3)2CRPCl2)
under vacuum results in the
expulsion of two
equivalents of
chlorotrimethylsilane and the
ultimate formation of a new phosphaalkyne. This synthetic...
- + C2H5Cl The
resulting dialkylphosphonate is then
treated with
chlorotrimethylsilane before hydrolysis of the
siloxyphosphonate to
generate the desired...
- engines.
Trimethylsilanol cannot be
produced by
simple hydrolysis of
chlorotrimethylsilane as this
reaction leads to the
etherification product hexamethyldisiloxane...
- by
treating acetylene with
butyl lithium followed by
addition of
chlorotrimethylsilane: Li2C2 + 2 Me3SiCl → Me3SiC≡CSiMe3 + 2 LiCl
BTMSA is used as a nucleophile...
-
silylketene acetal,
which is
formed by
trapping the
lithium enolate with
chlorotrimethylsilane. Like the Bellus-Claisen (above), Ireland-Claisen rearrangement...
-
sources have
quite variable prices, and the most
economical is
chlorotrimethylsilane (TMS-Cl), a
Direct Process byproduct. The
trimethylsilyl ethers...
- to
induce branching and cross-linking in PDMS molecules,
while chlorotrimethylsilane serves to end
backbone chains,
limiting molecular weight. Other...
