-
Butyllithium may
refer to one of 5
isomeric organolithium reagents of
which 3 are
commonly used in
chemical synthesis: n-
Butyllithium,
abbreviated BuLi...
- n-
Butyllithium C4H9Li (abbreviated n-BuLi) is an
organolithium reagent. It is
widely used as a
polymerization initiator in the
production of elastomers...
- sec-
Butyllithium is an
organometallic compound with the
formula CH3CHLiCH2CH3,
abbreviated sec-BuLi or s-BuLi. This
chiral organolithium reagent is used...
- tert-
Butyllithium is a
chemical compound with the
formula (CH3)3CLi. As an
organolithium compound, it has
applications in
organic synthesis since it is...
- ring
system with a DMG
group 1
interacts with an
alkyllithium such as n-
butyllithium in its
specific aggregation state (hence (R-Li)n) to
intermediate 2 since...
-
reagents are the
butyllithiums. tert-
Butyllithium and sec-
butyllithium are
generally more
reactive and have
better selectivity than n-
butyllithium, however,...
-
reaction of
preformed organolithium compounds: R−Li + R′−X → R−X + R′−Li
Butyllithium is
commonly used.
Gilman and
Wittig independently discovered this method...
- (scheme 1), the
alkyne proton of
ethyl propiolate is
deprotonated by n-
butyllithium at -78 °C to form
lithium ethyl propiolate to
which cyclopentanone is...
-
readily (e.g., gasoline, acetylene, propane,
hydrogen gas, diborane, tert-
Butyllithium).
Includes pyrophoric substances.
Flash point below room temperature...
-
hydrides (diethylaluminium hydride, trimethylaluminium, triethylaluminium,
butyllithium), with a few
exceptions (i.e.
dimethylmercury and tetraethyllead) Copper...
