- the pKa (enhances the acidity) by a million-fold. The
stability of
arenediazonium salts is
highly sensitive to the counterion.
Phenyldiazonium chloride...
- 1021/jo00434a017. Galli,
Carlo (August 1988). "Radical
reactions of
arenediazonium ions: An easy
entry into the
chemistry of the aryl radical". Chemical...
- Aryl
triflates can also be emplo****
instead of aryl halides.
Arenediazonium salts have been
reported as an
alternative to aryl
halides for the Sonogashira...
- Rogers, R. J. (1975). "Mechanism of
formation of aryl
fluorides from
arenediazonium fluoborates". J. Am. Chem. Soc. 97 (4): 799–800. doi:10.1021/ja00837a019...
-
arylation of
olefins that uses
arenediazonium salts as an
alternative to aryl
halides and triflates. The use of
arenediazonium salts presents some advantages...
- form benzaldehydes. In the
Sandmeyer reaction, the
treatment of an
arenediazonium salt with CuCl
leads to an aryl chloride. For example: The reaction...
- 1310. In
organic chemistry, H3PO2 can be used for the
reduction of
arenediazonium salts,
converting ArN+ 2 to Ar–H. When
diazotized in a concentrated...
- synthesis. A
useful application is in the
preparation of aryl
iodides from
arenediazonium salts. KI,
acting as a
source of iodide, may also act as a nucleophilic...
- Cardoso, F. S. P.; Correia, C. R. D. Heck
arylation of
styrenes with
arenediazonium salts: Short, efficient, and
stereoselective synthesis of resveratrol...
-
Intermolecular Olefin Functionalisation Involving Aryl
Radicals Generated from
Arenediazonium Salts Markus R.
Heinrich doi:10.1002/chem.200801306
Chemistry - A European...
