- In
chemistry and
molecular physics,
fluxional (or non-rigid)
molecules are
molecules that
undergo dynamics such that some or all of
their atoms interchange...
-
metal cyclopentadienyl complexes and has
attracted interest for its
fluxional structure.
Trimethylsilyl cyclopentadiene is an
example of a
molecule that...
-
calculations indicate that the compound's
point group is C3v. It is a
fluxional molecule. Oh is only
insignificantly higher,
indicating that the minimum...
-
carbon atom
covalently bonded to five
hydrogen atoms) or [CH3(H2)]+ (
fluxional form,
namely a
molecule with one
carbon atom
covalently bonded to three...
-
forming and
breaking rapidly on the NMR timescale; this
property makes it a
fluxional molecule. The
bullvalene molecule is a
cyclopropane platform with three...
- for
either tautomer is InChI=1S/C5H5NO/c7-5-3-1-2-4-6-5/h1-4H,(H,6,7).
Fluxional molecule "tautomer".
Oxford Dictionaries - English.
Archived from the...
-
bridging CO
ligands resulting in C2v symmetry. In solution, Os3(CO)12 is
fluxional as
indicated by 13C NMR measurements. The
barrier is
estimated at 70 kJ/mol...
-
February 2006). "Mechanisms that
Interchange Axial and
Equatorial Atoms in
Fluxional processes:
Illustration of the
Berry Pseudorotation, the
Turnstile and...
-
related to Mesomerism. Hückel
molecular orbital theory Conjugated system Fluxional molecule Avoided crossing Goudard, N.; Carissan, Y.; Hagebaum-Reignier...
-
adopt D3h-symmetric
structures,
wherein all 12 CO
ligands are
terminally bound to the metals. In
solution Fe3(CO)12 is
fluxional,
resulting in equivalencing...
