-
Trimethylsilylacetylene is the
organosilicon compound with the
formula (CH3)3Si−C≡CH. A
colorless liquid, "tms acetylene", as it is also called, is used...
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Sonogashira coupling of two
equivalents of 1-bromo-4-iodobenzene with
trimethylsilylacetylene (with the
trimethylsilyl group removed in-situ) to form...
-
another method involves the
Sonogashira coupling of
iodobenzene with
trimethylsilylacetylene,
followed by
removal of the
trimethylsilyl group using TBAF. Phenylacetylene...
- OCMe2 In this regard, 2-methylbut-3-yn-2-ol is used
similarly to
trimethylsilylacetylene.
Donald D.
Coffman (1940). "Dimethylethynylcarbinol". Org. Synth...
- rimethylsilyl)-2-propynyl]-amine from Cyclohexanecarbaldehyde,
Trimethylsilylacetylene and Dibenzylamine" Org. Synth. 2007, 84, 1. doi:10.15227/orgsyn...
- (H2SiF6)
Treatment with HCl in THF/water
solution Trimethylsilanol Trimethylsilylacetylene Trimethylsilyl chloride and fluoride [zh]
Tetramethylsilane Gottlieb...
- as
Suzuki coupling. In a
Sonogashira coupling it
couples with
trimethylsilylacetylene to form 4-((trimethylsilyl)ethynyl)benzaldehyde,
precursor to...
- the stomach,
which is
executed through Sonogashira coupling with
trimethylsilylacetylene to
yield 3,5-dibromo(trimethylsilylethynyl)benzene. Attachment...
-
dissolves in
organic solvents. It is
prepared by
iodination of
trimethylsilylacetylene.
Although samples explode above 80 °C,
diiodoacetylene is the most...
- example, two
equivalents of 1-bromo-4-iodobenzene can
couple to
trimethylsilylacetylene in a room
temperature symmetrical Sonogashira coupling (with TMSA...
