- In chemistry,
stereoselectivity is the
property of a
chemical reaction in
which a
single reactant forms an
unequal mixture of
stereoisomers during a non-stereospecific...
- and
remove the auxiliary. However, in some
cases the only
available stereoselective methodology relies on
chiral auxiliaries and
these reactions tend to...
-
Kedishvili NY, Zou Q, et al. (August 2004). "Methylphenidate is
stereoselectively hydrolyzed by
human carboxylesterase CES1A1". The
Journal of Pharmacology...
-
ethyl substituent are diastereotopic.
Chiral reagents are
known to
stereoselectively modify such substituents. The name of the
group is
derived from the...
-
trichloroacetimidate to
encourage B
stereoselectivity through the
gauche effect. This
reasonable stereoselectivity is
clear through visualization of the...
- Finally, the
aldonic acid
lactone is
reduced with
sodium amalgam non-
stereoselectively to
produce heptose; two
isomers with both
stereoisomers at C2 are...
-
accepted as a
click chemistry reaction given the reactions' high yield,
stereoselectivity, high rate, and
thermodynamic driving force. The
reaction results...
-
Sharpless asymmetric dihydroxylation (also
called the
Sharpless bishydroxylation) is the
chemical reaction of an
alkene with
osmium tetroxide in the presence...
-
Kraus K,
Blood J,
Stevens A,
Miller JP, et al. (November 2020). "
Stereoselective Steady-State
Disposition and
Bioequivalence of
Brand and
Generic Bupropion...
- He is a two-time
Nobel laureate in
Chemistry known for his work on
stereoselective reactions and
click chemistry.
Sharpless was
awarded half of the 2001...
