- Metal–metal
bonds in
polyoxometalates are
normally absent and
owing to this property, F.
Albert Cotton opposed to
consider polyoxometalates as form of cluster...
- complexes,
polyoxometalates containing Mo(V), Mo(VI), and a
hetero atom such as
phosphorus or
silicon reduced isopolymolybdate complexes,
polyoxometalates containing...
- P4O10
gives various phosphates.
Adding aqueous base to MoO3
gives polyoxometalates.
Oxycations are rarer, some
examples being nitrosonium (NO+), vanadyl...
-
Annette (19
February 2020). "Incorporation of
CrIII into a
Keggin Polyoxometalate as a
Chemical Strategy to
Stabilize a
Labile {CrIIIO4} Tetrahedral...
- Sílvia Cláudia Loureiro; Caliman, Ednéia (2014). "Keggin
Structure Polyoxometalates".
Inorganic Syntheses:
Volume 36. Vol. 36. pp. 210–217. doi:10.1002/9781118744994...
- Dias, J. A.; Dias, S. C. L.; Caliman, E. (2014). "Keggin
Structure Polyoxometalates".
Inorganic Syntheses:
Volume 36.
Inorganic Syntheses. Vol. 36. p. 210-217...
- In chemistry, the
heteropolymetalates are a
subset of the
polyoxometalates,
which consist of
three or more
transition metal oxyanions linked together by...
- solution, they
convert to oxo
clusters by the
process of olation,
forming polyoxometalates. In some cases, the
products of
partial hydrolysis of
metal ion, described...
-
silicates (IDs 9.A, e.g.
olivine and
gadolinite supergroups)
Other inorganic polymers (e.g.
polyoxometalates; "polyphosphates", IDs 8.F) Minerals portal...
-
aldehydes and
diazoalkanes into an alkene. The
polyoxotechnetate (
polyoxometalate of technetium)
contains both Tc(V) and Tc(VII) in
ratio 4: 16 and is...
