-
Organophosphines are
organophosphorus compounds with the
formula PRnH3−n,
where R is an
organic substituent.
These compounds can be
classified according...
-
compounds with the
formula OPX3. When X =
alkyl or aryl,
these are
organophosphine oxides.
Triphenylphosphine oxide is an example. An
inorganic phosphine...
-
oxidation state with soft
ligands such as thioethers, thiolates, and
organophosphines. Au(I)
compounds are
typically linear. A good
example is Au(CN)−2,...
- one or more
phosphine ligands.
Almost always, the
phosphine is an
organophosphine of the type R3P (R = alkyl, aryl).
Metal phosphine complexes are useful...
-
formula R3−nHnPBH3. They are
Lewis acid-Lewis base
adducts derived from
organophosphines (PR3−nHn) and
borane (BH3). They are
generally colorless or
white solids...
- P–P bonds.
Examples include catenated derivatives of
phosphine and
organophosphines.
Compounds containing P=P
double bonds have also been observed, although...
-
pyramidal structure.
Phosphines are
compounds that
include PH3 and the
organophosphines,
which are
derived from PH3 by
substituting one or more
hydrogen atoms...
- of
phosphonium salts can be
prepared by
alkylation and
arylation of
organophosphines: PR3 + R'X → [PR3R'+]X− The
methylation of
triphenylphosphine is the...
- Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP) is a
large triaryl organophosphine whose strong Lewis-basic
properties make it
useful as an organocatalyst...
-
Triphenylphosphine oxide (often
abbreviated TPPO) is the
organophosphorus compound with the
formula O=P(C6H5)3, also
written as Ph3PO or PPh3O (Ph = C6H5)...
