-
general structure R2N–O•. It is
commonly known as a
nitroxyl radical or a
nitroxide,
however IUPAC discourages the use of
these terms, as they erroneously...
-
Nitroxide-mediated
radical polymerization is a
method of
radical polymerization that
makes use of an
nitroxide initiator to
generate polymers with well...
- short-lived
intermediate in the
solution phase. The
conjugate base, NO−,
nitroxide anion, is the
reduced form of
nitric oxide (NO) and is
isoelectronic with...
-
which are
stabilized by
steric and/or
resonance effects. For example, the
nitroxide radical in (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO), the most common...
- Free-radical
polymerization Controlled radical polymerization ATRP RAFT
Nitroxide-mediated
radical polymerization Step-growth
polymerization Condensation...
-
September 2018. Damiani, E.; Greci, L.; Parsons, R.; Knowland, J. (1999). "
Nitroxide radicals protect DNA from
damage when
illuminated in
vitro in the presence...
- used as a
nitroxide spin label. MTSL is bifunctional,
consisting of the
nitroxide and the
thiosulfonate ester functional groups. The
nitroxide label is...
-
agents that lead to e.g. atom-transfer
radical polymerization (ATRP),
nitroxide-(aminoxyl)
mediated polymerization (NMP), or reversible-addition-fragmentation...
-
polymerization methods, such as atom-transfer radical-polymerization (ATRP),
nitroxide mediated radical polymerization (NMP), or
reversible addition−fragmentation...
-
oxidized to the
oxoammonium tetrafluoroborate.
TEMPO can also be emplo**** in
nitroxide-mediated
radical polymerization (NMP), a
controlled free
radical polymerization...
