- In
organic chemistry,
hydrocyanation is a
process for
conversion of
alkenes to nitriles. The
reaction involves the
addition of
hydrogen cyanide and requires...
- Industrially, the main
methods for
producing nitriles are
ammoxidation and
hydrocyanation. Both
routes are
green in the
sense that they do not
generate stoichiometric...
- by the use of a
superior HCN acceptor, such as an aldehyde. In the
hydrocyanation reaction of butadiene, the
transfer is irreversible. C****ava tubers...
-
Succinonitrile is
produced by the
addition of
hydrogen cyanide to
acrylonitrile (
hydrocyanation): CH2=CHCN + HCN → NCCH2CH2CN
Hydrogenation of
succinonitrile yields...
- 2004, the
majority of
adiponitrile is
prepared by the nickel-catalysed
hydrocyanation of butadiene, as
discovered at DuPont,
pioneered by
William C. Drinkard...
-
cyanide to each of the
double bonds in butadiene. The
process is
called hydrocyanation.
Butadiene is used to make the
solvent sulfolane.
Butadiene is also...
- such as
acetone cyanohydrin, Bill
Morandi and co-workers
developed a
hydrocyanation strategy using shuttle catalysis. In this example, they use isovaleronitrile...
-
alkenes under catalysis of
nickel complexes. This
reaction is
called hydrocyanation. RCH=CH2 + HCN → RCH2-CH2-CN Four
molecules of HCN will tetramerize...
-
derivative was used as a
phosphine ligand on
nickel in a
highly selective hydrocyanation reaction of butadiene. The
reactivity of this
catalyst is attributed...
-
reactions entail "HX additions"
where X =
silyl (hydrosilylation) and CN (
hydrocyanation). Most large-scale
industrial hydrogenations – margarine, ammonia,...
