- phosphines, carbenes, and nitrogen-based
coordination such as NacNac.
Dimethylberyllium has the same
crystal structure as
dimethylmagnesium and can be used...
- 1016/S0022-328X(00)82217-2. Snow, A.I.; Rundle, R.E. (1951). "Structure of
Dimethylberyllium". Acta Crystallographica. 4 (4): 348–52. doi:10.1107/S0365110X51001100...
-
surrounded by
bridging methyl groups. The Mg-C
distances are 224 pm.
Dimethylberyllium adopts the same structure. Cope, A. C. (1935). "The
Preparation of...
-
chlorodimethoxyborane 868-81-5 C2H6BFO2
fluorodimethoxyborane 367-46-4 C2H6Be
dimethylberyllium 506-63-8 C2H6ClOP
dimethylphosphinic chloride 1111-92-8 C2H6ClO2P...
-
trimethylsilyl azide: BeCl2 + 2 Me3SiN3 → Be(N3)2 + 2 Me3SiCl Alternatively,
dimethylberyllium reacts with
hydrazoic acid in dry
diethyl ether at −116 °C: Be(CH3)2...
- beryllium(II) compounds. It was
first synthesized in 1951 by
treating dimethylberyllium, Be(CH3)2, with
lithium aluminium hydride, LiAlH4.
Purer BeH2 forms...
-
focus towards inorganic and
organometallic chemistry,
publishing on
dimethylberyllium and its
reactivity with
Lewis bases, and the
reactivity of trimethylgallium...