- be
considered a
special case of half-sandwiches,
except that they are
dimetallic. A
structurally related species is [Ru(C6H6)Cl2]2. The
first isolated...
-
method metall- mine Gr**** μέταλλον (métallon), μεταλλικός (metallikós)
dimetallic, electrometallurgy, hydrometallurgy, metallic, metalloid, metallophobia...
-
atoms that are
directly bonded to each other. But metal-metal
bonded dimetallic complexes are
highly relevant to the area.
Clusters occur in "pure" inorganic...
-
method metall- mine Gr**** μέταλλον (métallon), μεταλλικός (metallikós)
dimetallic, electrometallurgy, hydrometallurgy, metallic, metalloid, metallophobia...
- a
uniquely stable 17-electron
metal carbonyl, is a blue-black solid.
Dimetallic and
polymetallic carbonyls tend to be more
deeply colored.
Triiron dodecacarbonyl...
-
synthesised in 1987 to
carry out
basic studies on the
redox chemistry of
dimetallic coordination compounds. Then, it was
serendipitously discovered by another...
- IrICl(CO)(PPh3)2 + H2 ⇌ H2IrIIICl(CO)(PPh3)2
Oxidative addition also can
occur to
dimetallic complexes, e.g.: Co 2(CO) 8 + H2 ⇌ 2 HCo(CO)4 Many
acids parti****te in...
- the
usual "clam-s****"
structure seen for
other Cp2MXn complexes. The
dimetallic structure has been
confirmed by
Microcrystal electron diffraction. The...
-
mixed salts display increased air and
moisture compared to the
parental dimetallic salts and show
Lewis acidity at the
rhodium center. Organobi****h chemistry...
- rule is used. Thus, 34
electrons in an
organometallic complex predicts a
dimetallic complex with a metal-metal bond. For
higher nuclearity clusters, more...
